Thermochemistry

Chemical system


First principle


Chemical equilibrium

Chemical system


State variables, phase concept, chemical reaction progress


Molar and partial molar quantities


Reaction quantities, Lewis operator, reference standard state.




First principle


First principle applied to chemical thermodynamics natural and reversible processes Internal energy and enthalpy isobaric heat of reaction case of GPs and real fluids


Hess's law - Kirchhoff's law: Born-Haber cycle, lattice energy, binding energy




chemical equilibrium


Equilibrium condition, spontaneous evolution of a reaction


Equilibrium constant